Mechanistic pathways of aromatic nucleophilic substitution in conventional solvents and ionic liquids
Journal
New J. Chem.
ISSN
1144-0546
1369-9261
Date Issued
2014
Author(s)
Marcela Gazitúa
Ricardo A. Tapia
Renato Contreras
Type
Resource Types::text::journal::journal article
URL Institutional Repository
Abstract
<p>Solvation effects on the reaction mechanism for nucleophilic substitution reactions have been kinetically evaluated in conventional solvents and ionic liquids.</p>
Subjects
solvation energy relationships
;
secondary-amines
;
snar reactions
;
aryl azides
;
benzenesulfonates
;
regioselectivity
;
kinetics
;
1-fluoro-2
;
4-dinitrobenzene
;
rationalization
;
acetonitrile