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  4. Solvent effect on a model SNAr reaction in ionic liquid/water mixtures at different compositions
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Solvent effect on a model SNAr reaction in ionic liquid/water mixtures at different compositions

Journal
New Journal of Chemistry
ISSN
1144-0546
1369-9261
Date Issued
2018
Author(s)
Bruno Sánchez
Cristian Calderón
Constanza Garrido
Renato Contreras
CAMPODONICO GALDAMES, PAOLA ROSSANA  
Facultad de Medicina Clínica Alemana Universidad del Desarrollo  
Type
Resource Types::text::journal::journal article
Scopus ID
2-s2.0-85048384202
WoS ID
WOS:000435298100034
DOI
10.1039/c7nj04820c
URL
https://investigadores.udd.cl/handle/123456789/2652
URL Institutional Repository
http://hdl.handle.net/11447/6105
Abstract
<p>A biphasic behavior observed on the reaction rate of a model S<sub>N</sub>Ar reaction in ionic liquid/water mixtures was explained by preferential solvation effects in water rich mixtures, and an anion effect in mixtures with high ionic liquid content.</p>
Project(s)
Experimental & Theoretical Studies on Nucleophilic Substitution Reactions in Solvents of Varying Polarity  
Subjects
aromatic nucleophilic-substitution

; 

preferential solvation

; 

binary-mixtures

; 

mixed-solvents

; 

nitro-group

; 

liquids

; 

water

; 

molecules

; 

catalysis

; 

kinetics
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