Production of Graphite Nanoplatelets via Functionalized Polyketone-Assisted Diels–Alder Chemistry: Evidence of Reduced Layer Thickness and Enhanced Exfoliation Efficiency
Journal
Polymers
ISSN
2073-4360
Date Issued
2025-05-14
Author(s)
Ricardo Cisternas
Jaime Orellana
Jonathan Correa-Puerta
Andrea Pucci
Ranjita K. Bose
Francesco Picchioni
Esteban Araya-Hermosilla
Rodrigo Araya-Hermosilla
Type
journal-article
URL Institutional Repository
Abstract
This study introduces an efficient and scalable method for the top-down exfoliation of graphite into graphite nanoplatelets (GNPs) using polyketones (PKs) functionalized with Diels–Alder (DA) active groups. Leveraging the reversible covalent interactions facilitated by furan and thiophene moieties in PK, combined with melt-mixing and shear force, this process achieves significant exfoliation while preserving the structural integrity of the resulting material. Thermal and rheological analyses demonstrate enhanced interfacial adhesion and stability within polymer composites attributed to the DA-driven interactions between functionalized PK and graphite. Comparative evaluations demonstrate that furan-functionalized PK exhibits superior exfoliation efficiency, highlighting its potential for producing high-quality exfoliated graphite suitable for advanced nanocomposite applications that require enhanced thermal, mechanical, and electrical properties. This method seamlessly integrates sustainability with industrial scalability, offering significant advancements in developing GNP-based materials.
Subjects
exfoliation (materials science)
;
graphene nanoplatelets
;
diels-alder
;
diels-alder reaction
;
exfoliation
;
functionalized
;
graphite nanoplates
;
nanoplatelet
;
paal-knorr reaction
;
polyketones
;
polymer intercalation
;
thermal
;
nanocomposites
;
diels–alder reaction
;
exfoliation
;
graphite
;
graphite nanoplates
;
nanocomposite
;
paal–knorr reaction
;
polyketone
;
polymer intercalation