Effect of the nature of the nucleophile and solvent on an SNAr reaction
Journal
New Journal of Chemistry
ISSN
1144-0546
1369-9261
Date Issued
2018
Author(s)
Marcela Gazitúa
Ricardo A. Tapia
Renato Contreras
Type
Resource Types::text::journal::journal article
URL Institutional Repository
Abstract
<p>The reaction of 2,4-dinitrobenzenesulfonyl chloride toward propylamine was kinetically evaluated in 19 organic solvents and 10 ionic liquids as reaction media.</p>
Subjects
temperature ionic liquids
;
preferential solvation
;
aromatic substitutions
;
conventional solvents
;
reaction-mechanism
;
aryl azides
;
kinetics
;
amines
;
1-fluoro-2
;
6-dinitrobenzene
;
regioselectivity